Literature DB >> 17338542

Palladium-catalyzed anti-hydrothiolation of 1-alkynylphosphines.

Azusa Kondoh1, Hideki Yorimitsu, Koichiro Oshima.   

Abstract

[structure: see text]. Treatment of 1-alkynylphosphine with thiol in the presence of a catalytic amount of palladium acetate results in regio- and stereoselective anti-hydrothiolation, yielding the corresponding (Z)-1-phosphino-2-thio-1-alkene.

Entities:  

Year:  2007        PMID： 17338542     DOI： 10.1021/ol0702876

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Mechanism of the palladium-catalyzed hydrothiolation of alkynes to thioethers: a DFT study.

Authors:  Xing-hui Zhang; Zhi-yuan Geng; Ke-tai Wang; Shan-shan Li
Journal:  J Mol Model       Date:  2014-08-20       Impact factor: 1.810

2.  Hydrothiolation of benzyl mercaptan to arylacetylene: application to the synthesis of (E) and (Z)-isomers of ON 01910·Na (Rigosertib®), a phase III clinical stage anti-cancer agent.

Authors:  Venkat R Pallela; Muralidhar R Mallireddigari; Stephen C Cosenza; Balaiah Akula; D R C Venkata Subbaiah; E Premkumar Reddy; M V Ramana Reddy
Journal:  Org Biomol Chem       Date:  2013-02-06       Impact factor: 3.876

3.  TBAI-assisted direct C-H activation of indoles with β-E-styrene sulfonyl hydrazides: a stereoselective access to 3-styryl thioindoles.

Authors:  Saira Hafeez; Aamer Saeed
Journal:  RSC Adv       Date:  2021-04-27       Impact factor: 4.036

Review 4.  Metal Catalysis in Thiolation and Selenation Reactions of Alkynes Leading to Chalcogen-Substituted Alkenes and Dienes.

Authors:  Nikolai V Orlov
Journal:  ChemistryOpen       Date:  2015-09-09       Impact factor: 2.911
  4 in total

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