| Literature DB >> 17326687 |
Masanori Imai1, Masakazu Tanaka, Shinji Nagumo, Norio Kawahara, Hiroshi Suemune.
Abstract
Rh-catalyzed intermolecular hydroacylation between salicylaldehyde and alkenylnitriles proceeded at room temperature to preferentially give normal-hydroacylated products. Addition of CH3CN and NaOAc accelerated the Rh-catalyzed hydroacylation of monoolefins to exclusively produce the normal-hydroacylated products under mild reaction conditions. Plausible mechanisms for the regioselections are also described.Entities:
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Year: 2007 PMID： 17326687 DOI： 10.1021/jo062501u
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354