Literature DB >> 17326627

A RhII-AuII bimetallic core with a direct metal-metal bond.

Arthur J Esswein1, Jillian L Dempsey, Daniel G Nocera.   

Abstract

The d8...d10 heterobimetallic RhIAuI(tfepma)2(CNtBu)2Cl2 (1) complex (tfepma = bis[bis(trifluoroethoxy)phosphino]methylamine) is oxidized by KAuIIICl4 to give the first structurally characterized d7-d9 RhII-AuII singly bonded metal complex [RhIIAuII(tfepma)2(CNtBu)2Cl3]+[AuICl2]- (2). Complex 2 undergoes a thermal intermetal redox reaction to generate fac-RhIII(tfepma)(CNtBu)Cl3 (3) and Au2I,I(tfepma)2Cl2 (4).

Entities:  

Year:  2007        PMID： 17326627     DOI： 10.1021/ic062203f

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  4 in total

1.  Chemistry of personalized solar energy.

Authors:  Daniel G Nocera
Journal:  Inorg Chem       Date:  2009-11-02       Impact factor: 5.165

2.  Halogen Photoelimination from Dirhodium Phosphazane Complexes via Chloride-Bridged Intermediates.

Authors:  David C Powers; Matthew B Chambers; Thomas S Teets; Noémie Elgrishi; Bryce L Anderson; Daniel G Nocera
Journal:  Chem Sci       Date:  2013-07-01       Impact factor: 9.825

3.  {N,N-Bis[bis-(2,2,2-tri-fluoro-eth-oxy)phosphan-yl]methyl-amine-κ(2) P,P'}bis-(η(5)-cyclo-penta-dien-yl)titanium(II).

Authors:  Martin Haehnel; Sven Hansen; Anke Spannenberg; Torsten Beweries
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-05-31

4.  Photocrystallographic observation of halide-bridged intermediates in halogen photoeliminations.

Authors:  David C Powers; Bryce L Anderson; Seung Jun Hwang; Tamara M Powers; Lisa M Pérez; Michael B Hall; Shao-Liang Zheng; Yu-Sheng Chen; Daniel G Nocera
Journal:  J Am Chem Soc       Date:  2014-10-21       Impact factor: 15.419
  4 in total

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