Literature DB >> 17325803

Monomeric, two-coordinate Mn, Fe and Co(II) complexes featuring 2,6-(2,4,6-trimethylphenyl)phenyl ligands.

Deborah L Kays1, Andrew R Cowley.   

Abstract

The synthesis and characterization of the monomeric, two-coordinate transition-metal complexes (2,6-Mes(2)C(6)H(3))(2)M (Mes = mesityl, 2,4,6-Me(3)C(6)H(2), M = Mn, Fe, Co) are reported; (2,6-Mes(2)C(6)H(3))(2)Co is the first structurally authenticated two-coordinate, homoleptic cobalt(II) complex featuring sigma-bonded aryl ligands.

Entities:  

Year:  2007        PMID： 17325803     DOI： 10.1039/b616584b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Direct spectroscopic observation of large quenching of first-order orbital angular momentum with bending in monomeric, two-coordinate Fe(II) primary amido complexes and the profound magnetic effects of the absence of Jahn- and Renner-Teller distortions in rigorously linear coordination.

Authors:  W Alexander Merrill; Troy A Stich; Marcin Brynda; Gregory J Yeagle; James C Fettinger; Raymond De Hont; William M Reiff; Charles E Schulz; R David Britt; Philip P Power
Journal:  J Am Chem Soc       Date:  2009-09-09       Impact factor: 15.419

2.  Selective reduction and homologation of carbon monoxide by organometallic iron complexes.

Authors:  Helen R Sharpe; Ana M Geer; Laurence J Taylor; Benjamin M Gridley; Toby J Blundell; Alexander J Blake; E Stephen Davies; William Lewis; Jonathan McMaster; David Robinson; Deborah L Kays
Journal:  Nat Commun       Date:  2018-09-14       Impact factor: 14.919
  2 in total

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