| Literature DB >> 17316013 |
Abstract
A chiral diamine was found to catalyze enantioselective addition of ketones to nitroolefins in aqueous/saline/organic media. The products were obtained with excellent diastereoselectivities (syn/anti = 99:1) and enantioselectivities up to 99%. The reaction could be facilitated using a mild acid. [reaction: see text]Entities:
Year: 2007 PMID： 17316013 DOI： 10.1021/ol070082x
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005