Literature DB >> 17311460

The use of chiral BINAM NHC-Rh(III) complexes in enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters.

Qin Xu1, Xingxing Gu, Sijia Liu, Qinyu Dou, Min Shi.   

Abstract

Axially chiral BINAM N-heterocyclic carbene (NHC)-Rh(III) complexes were applied in the enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters. The reduction products 3-hydroxy-3-arylpropionic acid methyl or ethyl esters could be obtained in good yields with good to excellent enantioselectivities under mild conditions.

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Year:  2007        PMID： 17311460     DOI： 10.1021/jo062453d

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Steric modulation of chiral biaryl diamines via Pd-catalyzed directed C-H arylation.

Authors:  Christopher C Scarborough; Richard I McDonald; Caroline Hartmann; Graham T Sazama; Ana Bergant; Shannon S Stahl
Journal:  J Org Chem       Date:  2009-03-20       Impact factor: 4.354

2.  Synthesis of chiral mono(N-heterocyclic carbene) palladium and gold complexes with a 1,1'-biphenyl scaffold and their applications in catalysis.

Authors:  Lian-Jun Liu; Feijun Wang; Wenfeng Wang; Mei-Xin Zhao; Min Shi
Journal:  Beilstein J Org Chem       Date:  2011-05-04       Impact factor: 2.883

3.  Demonstration of redox potential of Metschnikowia koreensis for stereoinversion of secondary alcohols/1,2-diols.

Authors:  Vachan Singh Meena; Linga Banoth; U C Banerjee
Journal:  Biomed Res Int       Date:  2014-01-27       Impact factor: 3.411
  3 in total

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