Literature DB >> 17308660

Mn2 bis(pentalene): a mixed-spin bimetallic with two extremes of bonding within the same molecule.

Gabor Balazs1, F Geoffrey N Cloke, Andrew Harrison, Peter B Hitchcock, Jennifer Green, Owen T Summerscales.   

Abstract

Structural, magnetic and theoretical studies show that the bimetallic pentalene complex, Mn(2)(C(8)H(4)(1,4-Si(i)Pr(3)))(2), contains both high and low spin Mn(ii) in two very different sites.

Entities:  

Year:  2006        PMID： 17308660     DOI： 10.1039/b614765h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Bis(heptalene) "submarine" metal dimer sandwich compounds (C12H10)2M2 (M = Ti, V, Cr, Mn, Fe, Co, Ni).

Authors:  Huidong Li; Hao Feng; Weiguo Sun; Qunchao Fan; Yaoming Xie; R Bruce King; Henry F Schaefer
Journal:  J Mol Model       Date:  2012-08-14       Impact factor: 1.810

2.  Bonding in Complexes of Bis(pentalene)dititanium, Ti2(C8H6)2.

Authors:  Alexander F R Kilpatrick; Jennifer C Green; F Geoffrey N Cloke
Journal:  Organometallics       Date:  2015-07-05       Impact factor: 3.876

3.  The Reductive Activation of CO2 Across a Ti=Ti Double Bond: Synthetic, Structural, and Mechanistic Studies.

Authors:  Alexander F R Kilpatrick; Jennifer C Green; F Geoffrey N Cloke
Journal:  Organometallics       Date:  2015-07-04       Impact factor: 3.876
  3 in total

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