Literature DB >> 17308654

Conversion of a (sp3)C-F bond of alkyl fluorides to (sp3)C-X (X = Cl, C, H, O, S, Se, Te, N) bonds using organoaluminium reagents.

Jun Terao1, Shameem Ara Begum, Yoshiaki Shinohara, Masahiro Tomita, Yoshitaka Naitoh, Nobuaki Kambe.   

Abstract

A simple method for the conversion of (sp(3))C-F bonds of alkyl fluorides to (sp(3))C-X (X = Cl, C, H, O, S, Se, Te, N) bonds has been achieved by the use of a hexane solution of organoaluminum reagents having Al-X bonds.

Entities:  

Year:  2006        PMID： 17308654     DOI： 10.1039/b613641a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  Vessel effects in organic chemical reactions; a century-old, overlooked phenomenon.

Authors:  Michael Martin Nielsen; Christian Marcus Pedersen
Journal:  Chem Sci       Date:  2022-05-04       Impact factor: 9.969

2.  Nickel-catalyzed coupling reaction of alkyl halides with aryl Grignard reagents in the presence of 1,3-butadiene: mechanistic studies of four-component coupling and competing cross-coupling reactions.

Authors:  Takanori Iwasaki; Asuka Fukuoka; Wataru Yokoyama; Xin Min; Ichiro Hisaki; Tao Yang; Masahiro Ehara; Hitoshi Kuniyasu; Nobuaki Kambe
Journal:  Chem Sci       Date:  2018-01-05       Impact factor: 9.825
  2 in total

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