Literature DB >> 17299642

An efficient biomimetic Fe-catalyzed epoxidation of olefins using hydrogen peroxide.

Gopinathan Anilkumar1, Bianca Bitterlich, Feyissa Gadissa Gelalcha, Man Kin Tse, Matthias Beller.   

Abstract

A new, environmentally benign and practical epoxidation method was developed using inexpensive and efficient Fe catalysts. FeCl3.6H2O in combination with commercially available pyridine-2,6-dicarboxylic acid and amines showed excellent reactivity and selectivity towards aromatic olefins and moderate reactivity towards 1,3-cyclooctadiene utilizing H2O2 as the terminal oxidant.

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Year:  2006        PMID: 17299642     DOI: 10.1039/b612048b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.

Authors:  Giorgio Olivo; Olaf Cussó; Margarida Borrell; Miquel Costas
Journal:  J Biol Inorg Chem       Date:  2017-01-25       Impact factor: 3.358

2.  A Bottom Up Approach Towards Artificial Oxygenases by Combining Iron Coordination Complexes and Peptides.

Authors:  Olaf Cusso; Michael W Giuliano; Xavi Ribas; Scott J Miller; Miquel Costas
Journal:  Chem Sci       Date:  2017-03-03       Impact factor: 9.825

  2 in total

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