Literature DB >> 17298077

Enantioselective synthesis of P-stereogenic benzophospholanes via palladium-catalyzed intramolecular cyclization.

Tim J Brunker1, Brian J Anderson, Natalia F Blank, David S Glueck, Arnold L Rheingold.   

Abstract

Enantioselective or diastereoselective intramolecular cyclization of functionalized secondary phosphines or their borane adducts catalyzed by chiral Pd(diphosphine) complexes gave P-stereogenic benzophospholanes in up to 70% ee. These results provide a new method for the synthesis of chiral phospholanes, which are valuable ligands in asymmetric catalysis. [reaction: see text]

Entities:  

Year:  2007        PMID： 17298077     DOI： 10.1021/ol0700512

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Direct visible-light-induced synthesis of P-stereogenic phosphine oxides under air conditions.

Authors:  Ying Zhang; Jia Yuan; Guanglong Huang; Hong Yu; Jinpeng Liu; Jian Chen; Sixuan Meng; Jian-Ji Zhong; Li Dang; Guang-Ao Yu; Chi-Ming Che
Journal:  Chem Sci       Date:  2022-04-25       Impact factor: 9.969

2.  Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis.

Authors:  James Stephen Harvey; Steven J Malcolmson; Katherine S Dunne; Simon J Meek; Amber L Thompson; Richard R Schrock; Amir H Hoveyda; Véronique Gouverneur
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

Review 3.  Preparation of phosphines through C-P bond formation.

Authors:  Iris Wauters; Wouter Debrouwer; Christian V Stevens
Journal:  Beilstein J Org Chem       Date:  2014-05-09       Impact factor: 2.883
  3 in total

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