Literature DB >> 17280428

Contribution of slow clusters to the bulk elasticity near the colloidal glass transition.

Jacinta C Conrad1, Param P Dhillon, Eric R Weeks, David R Reichman, David A Weitz.   

Abstract

We use confocal microscopy to visualize individual particles near the colloidal glass transition. We identify the most slowly-relaxing particles and show that they form spatially correlated clusters that percolate across the sample. In supercooled fluids, the largest cluster spans the system on short time scales but breaks up on longer time scales. In contrast, in glasses, a percolating cluster exists on all accessible time scales. Using molecular dynamics simulation, we show that these clusters make the dominant contribution to the bulk elasticity of the sample.

Year:  2006        PMID: 17280428     DOI: 10.1103/PhysRevLett.97.265701

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  6 in total

1.  Soft glassy rheology of supercooled molecular liquids.

Authors:  Rob Zondervan; Ted Xia; Harmen van der Meer; Cornelis Storm; Florian Kulzer; Wim van Saarloos; Michel Orrit
Journal:  Proc Natl Acad Sci U S A       Date:  2008-03-24       Impact factor: 11.205

2.  The relationship of dynamical heterogeneity to the Adam-Gibbs and random first-order transition theories of glass formation.

Authors:  Francis W Starr; Jack F Douglas; Srikanth Sastry
Journal:  J Chem Phys       Date:  2013-03-28       Impact factor: 3.488

3.  Cooling-rate induced softening in a colloidal glass.

Authors:  Yunzhuo Lu; Zhihua Zhang; Xing Lu; Zuoxiang Qin; Jun Shen; Yongjiang Huang; Peter K Liaw
Journal:  Sci Rep       Date:  2017-12-04       Impact factor: 4.379

4.  Structural and dynamical characteristics of flow units in metallic glasses.

Authors:  S T Liu; F X Li; M Z Li; W H Wang
Journal:  Sci Rep       Date:  2017-09-14       Impact factor: 4.379

5.  Fragility and Strength in Nanoparticle Glasses.

Authors:  Pieter van der Scheer; Ties van de Laar; Jasper van der Gucht; Dimitris Vlassopoulos; Joris Sprakel
Journal:  ACS Nano       Date:  2017-07-03       Impact factor: 15.881

6.  Probing the glass transition in reversible cross-linked polymer composites.

Authors:  Yong-Jin Peng; Chen-Ting Cai; Chang-Jun Wang; Zhong-Fu Zuo; Xue-Zheng Liu
Journal:  RSC Adv       Date:  2019-05-16       Impact factor: 3.361

  6 in total

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