| Literature DB >> 17279812 |
Sacramento Ferrer1, Elena Aznar, Francesc Lloret, Alfonso Castiñeiras, Malva Liu-González, Joaquín Borrás.
Abstract
The reaction of copper(II) sulfate, copper(II) chloride, 3,5-diacetylamino-1,2,4-triazole, and 3-acetylamino-5-amino-1,2,4-triazole in water yields green, plate-shaped crystals of [[{Cu3(mu3-OH(1/2))L(H2O)2Cl}2{mu-Cu(H2O)2Cl2}].12H2O]n (1), where L is a new triazole-derived macrocyclic ligand. The structure of 1 consists of heptanuclear (H)OCuII(3)-CuII-CuII(3)O(H) entities linked in pairs through symmetric mu3-O...H...O-mu3 hydrogen bonds to form a double-stranded one-dimensional network. A significant overall antiferromagnetic behavior has been observed for 1.Entities:
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Year: 2007 PMID： 17279812 DOI： 10.1021/ic0619106
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165