Literature DB >> 17269764

Resolution of enantiomers in solution and determination of the chirality of extended metal atom chains.

Daniel W Armstrong1, F Albert Cotton, Ana G Petrovic, Prasad L Polavarapu, Molly M Warnke.   

Abstract

The resolution of enantiomers of extended metal atom chains of the type Ni3[(C5H5N)2N]4Cl2 has been accomplished by chromatographic methods in solution, and the chirality was determined using vibrational circular dichroism, electronic circular dichroism, optical rotatory dispersion, and density functional theory calculations.

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Year:  2007        PMID: 17269764     DOI: 10.1021/ic062263l

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  2 in total

Review 1.  VCD studies on chiral characters of metal complex oligomers.

Authors:  Hisako Sato; Akihiko Yamagishi
Journal:  Int J Mol Sci       Date:  2013-01-07       Impact factor: 5.923

2.  Enantiomeric resolution and X-ray optical activity of a tricobalt extended metal atom chain.

Authors:  Anandi Srinivasan; Miguel Cortijo; Vladimir Bulicanu; Ahmad Naim; Rodolphe Clérac; Philippe Sainctavit; Andrei Rogalev; Fabrice Wilhelm; Patrick Rosa; Elizabeth A Hillard
Journal:  Chem Sci       Date:  2017-12-04       Impact factor: 9.825

  2 in total

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