Literature DB >> 17268673

Palladium-catalyzed silylation of alcohols with hexamethyldisilane.

Eiji Shirakawa1, Koji Hironaka, Hidehito Otsuka, Tamio Hayashi.   

Abstract

The combination of hexamethyldisilane and a catalytic amount of [PdCl(eta3-C3H5)]2-PPh3 was found to be effective for the trimethylsilylation of alcohols, where both of the two trimethylsilyl groups of hexamethyldisilane were transferred to alcohols without coproduction of any stoichiometric amount of byproduct but H2.

Entities:  

Year:  2006        PMID: 17268673     DOI: 10.1039/b608958e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Synthesis of an [(NHC)2 Pd(SiMe3 )2 ] Complex and Catalytic cis-Bis(silyl)ations of Alkynes with Unactivated Disilanes.

Authors:  Melvyn B Ansell; Debbie E Roberts; F Geoffrey N Cloke; Oscar Navarro; John Spencer
Journal:  Angew Chem Int Ed Engl       Date:  2015-04-09       Impact factor: 15.336

  1 in total

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