| Literature DB >> 17266320 |
Stefan Marchart1, Johann Mulzer, Valentin S Enev.
Abstract
[reaction: see text] Starting from (-)-quinic acid an efficient synthesis of highly functionalized cis-alpha,beta-unsaturated ketone 3, an advanced precursor of branimycin, has been accomplished via two key step reactions: a ring closing metathesis reaction to prepare the cis-decalin system, and a highly stereoselective epoxidation reaction.Entities:
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Year: 2007 PMID： 17266320 DOI： 10.1021/ol0630189
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005