| Literature DB >> 17264903 |
David R Armstrong1, William Clegg, Sophie H Dale, David V Graham, Eva Hevia, Lorna M Hogg, Gordon W Honeyman, Alan R Kennedy, Robert E Mulvey.
Abstract
Benzene can be easily 1,4-dideprotonated stoichiometrically on reaction with two equivalents of a synergic mixture of tBu2Zn, NaTMP and TMEDA to give a unique 1,4-dizincated benzene product which has been characterised by X-ray crystallography and NMR spectroscopy as well as modelled theoretically by DFT computational studies; a related synergic dimagnesiation of benzene is also reported.Entities:
Year: 2006 PMID： 17264903 DOI： 10.1039/b613655a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222