Literature DB >> 17243680

A mechanism for non-stoichiometry in the lithium amide/lithium imide hydrogen storage reaction.

William I F David1, Martin O Jones, Duncan H Gregory, Catherine M Jewell, Simon R Johnson, Allan Walton, Peter P Edwards.   

Abstract

We demonstrate, through structural refinement from synchrotron X-ray diffraction data, that the mechanism of the transformation between lithium amide and lithium imide during hydrogen cycling in the important Li-N-H hydrogen storage system is a bulk reversible reaction that occurs in a non-stoichiometric manner within the cubic anti-fluorite-like Li-N-H structure.

Entities:  

Year:  2007        PMID: 17243680     DOI: 10.1021/ja066016s

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  4 in total

1.  Low dimensional nanostructures of fast ion conducting lithium nitride.

Authors:  Nuria Tapia-Ruiz; Alexandra G Gordon; Catherine M Jewell; Hannah K Edwards; Charles W Dunnill; James M Blackman; Colin P Snape; Paul D Brown; Ian MacLaren; Matteo Baldoni; Elena Besley; Jeremy J Titman; Duncan H Gregory
Journal:  Nat Commun       Date:  2020-09-08       Impact factor: 14.919

2.  Lithium-nitrogen-hydrogen systems for ammonia synthesis: exploring a more efficient pathway using lithium nitride-hydride.

Authors:  Manoj Ravi; Joshua W Makepeace
Journal:  Chem Commun (Camb)       Date:  2022-05-20       Impact factor: 6.065

3.  Compositional flexibility in Li-N-H materials: implications for ammonia catalysis and hydrogen storage.

Authors:  Joshua W Makepeace; Jake M Brittain; Alisha Sukhwani Manghnani; Claire A Murray; Thomas J Wood; William I F David
Journal:  Phys Chem Chem Phys       Date:  2021-07-21       Impact factor: 3.676

4.  Ammonia decomposition catalysis using non-stoichiometric lithium imide.

Authors:  Joshua W Makepeace; Thomas J Wood; Hazel M A Hunter; Martin O Jones; William I F David
Journal:  Chem Sci       Date:  2015-05-07       Impact factor: 9.825

  4 in total

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