Literature DB >> 17205164

Acyl palladium species in synthesis: single-step synthesis of alpha,beta-unsaturated ketones from acid chlorides.

Russell J Cox1, Andrew S Evitt.   

Abstract

Conditions are reported for the facile, one-pot synthesis of alpha,beta-unsaturated ketones via the palladium-catalysed cross-coupling of acyl chlorides with hydrozirconated acetylenes, and its use in the 2-step synthesis of D-5-O-benzyl deoxyxylulose.

Entities:  

Year:  2006        PMID: 17205164     DOI: 10.1039/b616582f

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  1 in total

1.  Engineering of an "unnatural" natural product by swapping polyketide synthase domains in Aspergillus nidulans.

Authors:  Ting Liu; Yi-Ming Chiang; Amber D Somoza; Berl R Oakley; Clay C C Wang
Journal:  J Am Chem Soc       Date:  2011-08-10       Impact factor: 15.419

  1 in total

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