Literature DB >> 17192090

Singlet biradical character of phenalenyl-based Kekulé hydrocarbon with naphthoquinoid structure.

Takashi Kubo1, Akihiro Shimizu, Mikio Uruichi, Kyuya Yakushi, Masayoshi Nakano, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Yasushi Morita, Kazuhiro Nakasuji.   

Abstract

[reaction: see text] A new Kekulé polycyclic hydrocarbon with a singlet biradical index of 50% was synthesized. The singlet biradical character was assessed with UV and 1H-NMR spectroscopy, cyclic voltammetry, SQUID magnetic susceptibility measurement, and quantum chemical calculations.

Entities:  

Year:  2007        PMID: 17192090     DOI: 10.1021/ol062604z

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  6 in total

1.  Triplet fluoranthenes: aromaticity versus unpaired electrons.

Authors:  Svetlana Marković; Jelena Đurđević; Svetlana Jeremić; Ivan Gutman
Journal:  J Mol Model       Date:  2010-06-20       Impact factor: 1.810

2.  Nonacethrene Unchained: A Cascade to Chiral Contorted Conjugated Hydrocarbon with Two sp3-Defects.

Authors:  Daniel Čavlović; Daniel Häussinger; Olivier Blacque; Prince Ravat; Michal Juríček
Journal:  JACS Au       Date:  2022-07-09

3.  Dimethylcethrene: A Chiroptical Diradicaloid Photoswitch.

Authors:  Prince Ravat; Tomáš Šolomek; Daniel Häussinger; Olivier Blacque; Michal Juríček
Journal:  J Am Chem Soc       Date:  2018-08-17       Impact factor: 15.419

4.  Energetics and Electronic Structure of Triangular Hexagonal Boron Nitride Nanoflakes.

Authors:  Mina Maruyama; Susumu Okada
Journal:  Sci Rep       Date:  2018-11-09       Impact factor: 4.379

Review 5.  Recent Progress in High Linearly Fused Polycyclic Conjugated Hydrocarbons (PCHs, n > 6) with Well-Defined Structures.

Authors:  Wangqiao Chen; Fei Yu; Qun Xu; Guofu Zhou; Qichun Zhang
Journal:  Adv Sci (Weinh)       Date:  2020-04-22       Impact factor: 16.806

6.  Synthesis of open-shell ladder π-systems by catalytic C-H annulation of diarylacetylenes.

Authors:  Takehisa Maekawa; Hiroshi Ueno; Yasutomo Segawa; Michael M Haley; Kenichiro Itami
Journal:  Chem Sci       Date:  2015-10-22       Impact factor: 9.825

  6 in total

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