Literature DB >> 17177395

Isolation of a tetrameric cation-cation complex of pentavalent uranyl.

Fabien Burdet1, Jacques Pécaut, Marinella Mazzanti.   

Abstract

A polymetallic assembly containing mutually coordinated highly reactive UO2+ groups was isolated in the presence of dibenzoylmethanate. NMR studies showed unambiguously the presence of the cation-cation complex in pyridine solution while more polar solvents lead to the disruption of the UO2+/UO2+ interaction and increased stability.

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Year:  2006        PMID： 17177395     DOI： 10.1021/ja067445t

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  Uranium azide photolysis results in C-H bond activation and provides evidence for a terminal uranium nitride.

Authors:  Robert K Thomson; Thibault Cantat; Brian L Scott; David E Morris; Enrique R Batista; Jaqueline L Kiplinger
Journal:  Nat Chem       Date:  2010-07-11       Impact factor: 24.427

2.  Strongly coupled binuclear uranium-oxo complexes from uranyl oxo rearrangement and reductive silylation.

Authors:  Polly L Arnold; Guy M Jones; Samuel O Odoh; Georg Schreckenbach; Nicola Magnani; Jason B Love
Journal:  Nat Chem       Date:  2012-02-21       Impact factor: 24.427

3.  Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin.

Authors:  James R Pankhurst; Nicola L Bell; Markus Zegke; Lucy N Platts; Carlos Alvarez Lamfsus; Laurent Maron; Louise S Natrajan; Stephen Sproules; Polly L Arnold; Jason B Love
Journal:  Chem Sci       Date:  2016-10-28       Impact factor: 9.825

4.  The effect of iron binding on uranyl(v) stability.

Authors:  Radmila Faizova; Sarah White; Rosario Scopelliti; Marinella Mazzanti
Journal:  Chem Sci       Date:  2018-08-14       Impact factor: 9.825
  4 in total

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