| Literature DB >> 17177359 |
Silas P Cook1, Alessandra Polara, Samuel J Danishefsky.
Abstract
The total synthesis of the putative non-peptidyl neurotrophic factor 11-O-debenzoyltashironin has been accomplished. The key transformation involves a biomimetic oxidative dearomatization/transannular Diels-Alder sequence that closes the tetracyclic carbon skeleton present in the natural product.Entities:
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Year: 2006 PMID: 17177359 DOI: 10.1021/ja0670254
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419