Literature DB >> 17168623

RuCl3-catalyzed oxidation of iodoarenes with peracetic acid: new facile preparation of iodylarenes.

Alexey Y Koposov1, Rashad R Karimov, Andrey A Pronin, Tatyana Skrupskaya, Mekhman S Yusubov, Viktor V Zhdankin.   

Abstract

New facile methodology for the preparation of pentavalent iodine compounds using peracetic acid as an oxidant in the presence of catalytic amounts of ruthenium trichloride is described. The new procedure allows the preparation of several previously unknown iodylarenes bearing strongly electron-withdrawing CF3 groups in the aromatic ring.

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Year:  2006        PMID: 17168623     DOI: 10.1021/jo062073s

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

Review 1.  Chemistry of polyvalent iodine.

Authors:  Viktor V Zhdankin; Peter J Stang
Journal:  Chem Rev       Date:  2008-12       Impact factor: 60.622

2.  Preparation and X-ray structure of 2-iodoxybenzenesulfonic acid (IBS) - a powerful hypervalent iodine(V) oxidant.

Authors:  Irina A Mironova; Pavel S Postnikov; Rosa Y Yusubova; Akira Yoshimura; Thomas Wirth; Viktor V Zhdankin; Victor N Nemykin; Mekhman S Yusubov
Journal:  Beilstein J Org Chem       Date:  2018-07-20       Impact factor: 2.883

  2 in total

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