Literature DB >> 17146507

Sequential one-pot bimetallic Ir(III)/Pd(0) catalysed mono-/bis-alkylation and spirocyclisation processes of 1,3-dimethylbarbituric acid and allenes.

Christian Löfberg1, Ronald Grigg, Ann Keep, Andrew Derrick, Visuvanathar Sridharan, Colin Kilner.   

Abstract

Microwave assisted indirect functionalization of alcohols with 1,3-dimethylbarbituric acid followed by spirocyclisation employing a sequential one-pot Ir(III)/Pd(0) catalysed process, involving the formation of three new C-C bonds, one spirocyclic ring and one di- or tri-substituted exocyclic alkene, is described.

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Year:  2006        PMID: 17146507     DOI: 10.1039/b614098j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  Controlled microwave heating in modern organic synthesis: highlights from the 2004-2008 literature.

Authors:  C Oliver Kappe; Doris Dallinger
Journal:  Mol Divers       Date:  2009-04-21       Impact factor: 2.943

2.  Iron-Catalyzed Borrowing Hydrogen C-Alkylation of Oxindoles with Alcohols.

Authors:  Mubarak B Dambatta; Kurt Polidano; Alexander D Northey; Jonathan M J Williams; Louis C Morrill
Journal:  ChemSusChem       Date:  2019-05-07       Impact factor: 8.928

3.  Rhodium-catalyzed ketone methylation using methanol under mild conditions: formation of α-branched products.

Authors:  Louis K M Chan; Darren L Poole; Di Shen; Mark P Healy; Timothy J Donohoe
Journal:  Angew Chem Int Ed Engl       Date:  2013-11-29       Impact factor: 15.336

  3 in total

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