Literature DB >> 17136249

Acidic iridium hydrides: implications for aerobic and Oppenauer oxidation of alcohols.

Anders Gabrielsson1, Piet van Leeuwen, Wolfgang Kaim.   

Abstract

[Cp*Ir(H)(bpym)]+ and [Cp*Ir(H)(bpy)]+ are the first examples of iridium based catalysts for the aerobic oxidation of alcohols; the catalytic cycle proceeds via acidic hydrides. Deprotonation of the hydride leads to a highly oxygen sensitive Ir I species that regenerate the Ir III complexes upon oxidation with dioxygen.

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Year:  2006        PMID： 17136249     DOI： 10.1039/b610857a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Electron-Rich CpIr(biphenyl-2,2'-diyl) Complexes with π-Accepting Carbon Donor Ligands.

Authors:  Jonathan Graeupner; Timothy P Brewster; James D Blakemore; Nathan D Schley; Julianne M Thomsen; Gary W Brudvig; Nilay Hazari; Robert H Crabtree
Journal:  Organometallics       Date:  2012-10-20       Impact factor: 3.876

2.  Hydrogen-borrowing and interrupted-hydrogen-borrowing reactions of ketones and methanol catalyzed by iridium.

Authors:  Di Shen; Darren L Poole; Camilla C Shotton; Anne F Kornahrens; Mark P Healy; Timothy J Donohoe
Journal:  Angew Chem Int Ed Engl       Date:  2014-12-09       Impact factor: 15.336

3.  Rhodium-catalyzed ketone methylation using methanol under mild conditions: formation of α-branched products.

Authors:  Louis K M Chan; Darren L Poole; Di Shen; Mark P Healy; Timothy J Donohoe
Journal:  Angew Chem Int Ed Engl       Date:  2013-11-29       Impact factor: 15.336
  3 in total

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