Literature DB >> 17120117

Observed molecular alignment in gaseous streams and possible chiral effects in vortices and in surface scattering.

V Aquilanti1, G S Maciel.   

Abstract

Extensive work in this laboratory has been devoted to the study of intermolecular interactions from scattering experiments, in order to provide ingredients for modelling forces acting in systems involving hydrocarbons, the components of atmospheres, and water. Our detection of aligned oxygen in gaseous streams and further evidence on simple molecules has been extended to benzene and various hydrocarbons. Chiral effects can be seen in the differential scattering of oriented molecules, in particular from surfaces. It is pointed out that it may be of pre-biotical interest that we focus on possible mechanisms for chiral bio-stereochemistry of oriented reactants, for example when flowing in atmospheres of rotating bodies, specifically the planet earth, as well as in vortex motions of celestial objects. Molecular dynamics simulations and experimental verifications are in progress.

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Year:  2006        PMID: 17120117     DOI: 10.1007/s11084-006-9048-z

Source DB:  PubMed          Journal:  Orig Life Evol Biosph        ISSN: 0169-6149            Impact factor:   1.950


  12 in total

1.  Enantioselective magnetochiral photochemistry

Authors:  G L Rikken; E Raupach
Journal:  Nature       Date:  2000-06-22       Impact factor: 49.962

2.  Absolute Asymmetric Synthesis under Physical Fields: Facts and Fictions.

Authors:  Martín Avalos; Reyes Babiano; Pedro Cintas; José L. Jiménez; Juan C. Palacios; Laurence D. Barron
Journal:  Chem Rev       Date:  1998-11-05       Impact factor: 60.622

3.  Chiral sign induction by vortices during the formation of mesophases in stirred solutions.

Authors:  J M Ribó; J Crusats; F Sagués; J Claret; R Rubires
Journal:  Science       Date:  2001-06-15       Impact factor: 47.728

4.  Orientation of benzene in supersonic expansions, probed by IR-laser absorption and by molecular beam scattering.

Authors:  F Pirani; D Cappelletti; M Bartolomei; V Aquilanti; M Scotoni; M Vescovi; D Ascenzi; D Bassi
Journal:  Phys Rev Lett       Date:  2001-05-28       Impact factor: 9.161

5.  Stereodynamic effects in the adsorption of ethylene onto a metal surface.

Authors:  Luca Vattuone; Andrea Gerbi; Mario Rocca; Ugo Valbusa; Fernando Pirani; Franco Vecchiocattivi; David Cappelletti
Journal:  Angew Chem Int Ed Engl       Date:  2004-10-04       Impact factor: 15.336

6.  Atom-specific identification of adsorbed chiral molecules by photoemission.

Authors:  J W Kim; M Carbone; J H Dil; M Tallarida; R Flammini; M P Casaletto; K Horn; M N Piancastelli
Journal:  Phys Rev Lett       Date:  2005-09-02       Impact factor: 9.161

7.  Valence photoionization dynamics in circular dichroism of chiral free molecules: the methyl-oxirane.

Authors:  S Stranges; S Turchini; M Alagia; G Alberti; G Contini; P Decleva; G Fronzoni; M Stener; N Zema; T Prosperi
Journal:  J Chem Phys       Date:  2005-06-22       Impact factor: 3.488

8.  Stereodynamic effects in the adsorption of propylene molecules on Ag(001).

Authors:  A Gerbi; L Vattuone; M Rocca; F Pirani; U Valbusa; D Cappelletti; F Vecchiocattivi
Journal:  J Phys Chem B       Date:  2005-12-08       Impact factor: 2.991

9.  New insights on the stereodynamics of ethylene adsorption on an oxygen-precovered silver surface.

Authors:  Andrea Gerbi; Luca Vattuone; Mario Rocca; Ugo Valbusa; Fernando Pirani; David Cappelletti; Franco Vecchiocattivi
Journal:  J Chem Phys       Date:  2005-12-08       Impact factor: 3.488

10.  Orienting and aligning molecules for stereochemistry and photodynamics.

Authors:  Vincenzo Aquilanti; Massimiliano Bartolomei; Fernando Pirani; David Cappelletti; France Vecchiocattivi; Yuichiro Shimizu; Toshio Kasai
Journal:  Phys Chem Chem Phys       Date:  2005-01-21       Impact factor: 3.676

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  2 in total

1.  Selection of supramolecular chirality by application of rotational and magnetic forces.

Authors:  N Micali; H Engelkamp; P G van Rhee; P C M Christianen; L Monsù Scolaro; J C Maan
Journal:  Nat Chem       Date:  2012-02-12       Impact factor: 24.427

2.  Chiral biases in solids by effect of shear gradients: a speculation on the deterministic origin of biological homochirality.

Authors:  Oriol Arteaga; Adolf Canillas; Joaquim Crusats; Zoubir El-Hachemi; Gerald E Jellison; Jordi Llorca; Josep M Ribó
Journal:  Orig Life Evol Biosph       Date:  2009-11-13       Impact factor: 1.950

  2 in total

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