Literature DB >> 17117853

Efficient intermolecular [2 + 2 + 2] alkyne cyclotrimerization in aqueous medium using a ruthenium(IV) precatalyst.

Victorio Cadierno1, Sergio E García-Garrido, José Gimeno.   

Abstract

The dimeric bis(allyl)-ruthenium(IV) complex [{Ru(eta3:eta3-C10H16)(mu-Cl)Cl}2] (C10H16 = 2,7-dimethylocta-2,6-diene-1,8-diyl) was found to catalyze efficiently the [2 + 2 + 2] cyclization of terminal and internal alkynes in aqueous medium.

Entities:  

Year:  2006        PMID： 17117853     DOI： 10.1021/ja066552k

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

Review 1.  Ruthenium-Catalyzed Cycloadditions to Form Five-, Six-, and Seven-Membered Rings.

Authors:  Rosalie S Doerksen; Tomáš Hodík; Guanyu Hu; Nancy O Huynh; William G Shuler; Michael J Krische
Journal:  Chem Rev       Date:  2021-02-12       Impact factor: 60.622

2.  Enhanced Catalytic Activity of Nickel Complexes of an Adaptive Diphosphine-Benzophenone Ligand in Alkyne Cyclotrimerization.

Authors:  Alessio F Orsino; Manuel Gutiérrez Del Campo; Martin Lutz; Marc-Etienne Moret
Journal:  ACS Catal       Date:  2019-01-31       Impact factor: 13.084

3.  Intracellular Ruthenium-Promoted (2+2+2) Cycloadditions.

Authors:  Joan Miguel-Ávila; María Tomás-Gamasa; José L Mascareñas
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-11       Impact factor: 16.823
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.