Literature DB >> 17109057

First enantioselective organocatalytic allylation of simple aldimines with allyltrichlorosilane.

Sunil B Jagtap1, Svetlana B Tsogoeva.   

Abstract

A new organocatalytic system, novel chiral bisformamide and in situ generated L-proline-derived allylsilane reagent , which converts different aldimines to homoallylic amines in good to high yields (up to 95%) and good enantioselectivities (up to 85% ee) has been described.

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Year:  2006        PMID： 17109057     DOI： 10.1039/b611823b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Enantioselective, Catalytic Multicomponent Synthesis of Homoallylic Amines Enabled by Hydrogen-Bonding and Dispersive Interactions.

Authors:  Elisabetta Ronchi; Shauna M Paradine; Eric N Jacobsen
Journal:  J Am Chem Soc       Date:  2021-05-05       Impact factor: 15.419

2.  Catalyst free N-formylation of aromatic and aliphatic amines exploiting reductive formylation of CO2 using NaBH4.

Authors:  Arun Kumar; Pankaj Sharma; Nidhi Sharma; Yashwant Kumar; Dinesh Mahajan
Journal:  RSC Adv       Date:  2021-07-27       Impact factor: 4.036
  2 in total

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