Literature DB >> 17105288

High frequency dielectric response in a branched phthalocyanine.

Meng Guo1, Xingzhong Yan, Young Kwon, Teruaki Hayakawa, Masa-aki Kakimoto, Theodore Goodson.   

Abstract

We describe the dielectric effects in a novel branched phthalocyanine system. The synthesis and characterization of the hyperbranched structure are provided. The dielectric constant was approximately 45 over many decades of frequency, and the dispersion was small up to 1 MHz. The losses experienced in this novel material were very small (close to 0.001) at high frequency. The mechanism of this novel effect in the branched structure involves a delocalized polaronic state which takes advantage of the strong intramolecular interactions in the system.

Entities:  

Year:  2006        PMID: 17105288     DOI: 10.1021/ja063796w

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  2 in total

1.  Highly Soluble Benzo[ghi]perylenetriimide Derivatives: Stable and Air-Insensitive Electron Acceptors for Artificial Photosynthesis.

Authors:  Hung-Cheng Chen; Chao-Ping Hsu; Joost N H Reek; René M Williams; Albert M Brouwer
Journal:  ChemSusChem       Date:  2015-09-23       Impact factor: 8.928

2.  Active site formation mechanism of carbon-based oxygen reduction catalysts derived from a hyperbranched iron phthalocyanine polymer.

Authors:  Yusuke Hiraike; Makoto Saito; Hideharu Niwa; Masaki Kobayashi; Yoshihisa Harada; Masaharu Oshima; Jaehong Kim; Yuta Nabae; Masa-Aki Kakimoto
Journal:  Nanoscale Res Lett       Date:  2015-04-14       Impact factor: 4.703

  2 in total

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