Literature DB >> 17105283

Cyclic C-amino phosphorus ylides as a source of bidentate heteroditopic ligands (phosphine/aminocarbene) for transition metals.

Joan Vignolle1, Bruno Donnadieu, Didier Bourissou, Michèle Soleilhavoup, Guy Bertrand.   

Abstract

In contrast with most of their congeners, acyclic and cyclic C-amino phosphorus ylides behave as genuine carbene and phosphine transfer agents for transition metal centers. They allow the facile synthesis of a variety of metal complexes that feature heteroditopic ligands, such as 1,6-(phosphine)(aminocarbene) systems with a biphenyl backbone.

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Year:  2006        PMID： 17105283      PMCID： PMC2440677          DOI： 10.1021/ja0662725

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  10 in total

1.  A new general method for the preparation of metal carbene complexes.

Authors:  M Gandelman; B Rybtchinski; N Ashkenazi; R M Gauvin; D Milstein
Journal:  J Am Chem Soc       Date:  2001-06-06       Impact factor: 15.419

2.  Methylenation of Aldehydes: Transition Metal Catalyzed Formation of Salt-Free Phosphorus Ylides We thank the Charette group (Université de Montréal) for generously sharing their chemicals and equipment. This research was supported by NSERC (Canada), F.C.A.R (Québec), the Foundation for Innovation, and the Université de Montréal.

Authors:  Hélène Lebel; Valérie Paquet; Caroline Proulx
Journal:  Angew Chem Int Ed Engl       Date:  2001-08-03       Impact factor: 15.336

3.  Modified BINAP: the how and the why.

Authors:  Mikaël Berthod; Gérard Mignani; Gary Woodward; Marc Lemaire
Journal:  Chem Rev       Date:  2005-05       Impact factor: 60.622

4.  Asymmetric catalysis: science and opportunities (Nobel lecture).

Authors:  Ryoji Noyori
Journal:  Angew Chem Int Ed Engl       Date:  2002-06-17       Impact factor: 15.336

5.  Hemilability of Hybrid Ligands and the Coordination Chemistry of Oxazoline-Based Systems.

Authors:  Pierre Braunstein; Frédéric Naud
Journal:  Angew Chem Int Ed Engl       Date:  2001-02-16       Impact factor: 15.336

6.  A general method for preparation of metal carbenes via solution- and polymer-based approaches.

Authors:  Mark Gandelman; Kyaw M Naing; Boris Rybtchinski; Elena Poverenov; Yehoshoa Ben-David; Nissan Ashkenazi; Regis M Gauvin; David Milstein
Journal:  J Am Chem Soc       Date:  2005-11-02       Impact factor: 15.419

7.  Synthesis of transient and stable C-amino phosphorus ylides and their fragmentation into transient and stable carbenes.

Authors:  Yves Canac; Salvador Conejero; Michèle Soleilhavoup; Bruno Donnadieu; Guy Bertrand
Journal:  J Am Chem Soc       Date:  2006-01-18       Impact factor: 15.419

8.  Asymmetric catalytic hydrogenation. Design of new Ru catalysts and chiral ligands: from laboratory to industrial applications.

Authors:  Jean-Pierre Genet
Journal:  Acc Chem Res       Date:  2003-12       Impact factor: 22.384

9.  [ReO3(bipy)]+[X]--catalyzed aldehyde olefination: carbene and phosphorane intermediates.

Authors:  Xiangyang Zhang; Peter Chen
Journal:  Chemistry       Date:  2003-04-14       Impact factor: 5.236

10.  New synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines.

Authors:  Salvador Conejero; Maoying Song; David Martin; Yves Canac; Michele Soleilhavoup; Guy Bertrand
Journal:  Chem Asian J       Date:  2006-07-17
  10 in total
  1 in total

1.  Palladium-oxygen and palladium-arene interactions in complexes derived from biaryl aminocarbenes: comparison with biaryl phosphanes.

Authors:  Joan Vignolle; Heinz Gornitzka; Bruno Donnadieu; Didier Bourissou; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336
  1 in total

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