Literature DB >> 17091995

Selective extraction and purification of endohedral metallofullerene from carbon soot.

Takahiro Tsuchiya1, Takatsugu Wakahara, Yongfu Lian, Yutaka Maeda, Takeshi Akasaka, Tatsuhisa Kato, Naomi Mizorogi, Shigeru Nagase.   

Abstract

A preferential extraction of endohedral metallofullerenes (EMFs) from carbon soot through the use of reduction in the extraction process and a convenient isolation of endohedral metallofullerene anions (EMFs(-)) and empty fullerenes utilizing their difference in solubility are accomplished. EMFs are easily isolated by one-stage high-performance liquid chromatography after chemical oxidation of the extracted endohedral EMFs(-).

Entities:  

Year:  2006        PMID： 17091995     DOI： 10.1021/jp0650679

Source DB:  PubMed          Journal:  J Phys Chem B        ISSN： 1520-5207            Impact factor:   2.991


  3 in total

1.  Single molecule magnet with an unpaired electron trapped between two lanthanide ions inside a fullerene.

Authors:  Fupin Liu; Denis S Krylov; Lukas Spree; Stanislav M Avdoshenko; Nataliya A Samoylova; Marco Rosenkranz; Aram Kostanyan; Thomas Greber; Anja U B Wolter; Bernd Büchner; Alexey A Popov
Journal:  Nat Commun       Date:  2017-07-14       Impact factor: 14.919

Review 2.  Non-Chromatographic Purification of Endohedral Metallofullerenes.

Authors:  Zhiyong Wang; Haruka Omachi; Hisanori Shinohara
Journal:  Molecules       Date:  2017-04-29       Impact factor: 4.411

3.  Single-Electron Lanthanide-Lanthanide Bonds Inside Fullerenes toward Robust Redox-Active Molecular Magnets.

Authors:  Fupin Liu; Lukas Spree; Denis S Krylov; Georgios Velkos; Stanislav M Avdoshenko; Alexey A Popov
Journal:  Acc Chem Res       Date:  2019-10-01       Impact factor: 22.384
  3 in total

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