| Literature DB >> 17090026 |
Victoria Kravchenko1, Rei Kinjo, Akira Sekiguchi, Masaaki Ichinohe, Robert West, Yael S Balazs, Asher Schmidt, Miriam Karni, Yitzhak Apeloig.
Abstract
The first solid state 29Si NMR of a disilyne, that is, RSiSiR, R = Si(CH(SiMe3)2)2(i-Pr) (1) was measured: delta11 = 364 +/- 20; delta22 = 221 +/- 16 and delta33 = -350 +/- 13; CSA = -643 ppm. These measured values as well as calculations for model disilynes strongly support the description of the Si-Si bond in bent disilynes as a triple bond, although with weakened pi-bonds and a reduced bond order of 2.6.Entities:
Year: 2006 PMID： 17090026 DOI： 10.1021/ja065817s
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419