| Literature DB >> 17082848 |
Suad Rashdan1, Mark E Light, Jeremy D Kilburn.
Abstract
The binding selectivity of simple pyridyl thioureas in acetonitrile can be completely switched by protonation; hence the neutral thiourea binds acetate, but not chloride or bromide, whereas the protonated thiourea binds strongly to chloride or bromide, but is deprotonated by acetate.Entities:
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Year: 2006 PMID: 17082848 DOI: 10.1039/b611138f
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222