| Literature DB >> 17076491 |
Mark W Davies1, Michael Shipman, James H R Tucker, Tiffany R Walsh.
Abstract
The dynamics of pyramidal nitrogen inversion can be controlled by reversible redox switching in trans-2,3-diphenylaziridines bearing a suitable 1,4-naphthaquinone substituent. In the reduced form, an intramolecular H-bond significantly raises the inversion barrier slowing this molecular motion by >50-fold. The experimental findings are further supported by DFT calculations.Entities:
Year: 2006 PMID： 17076491 DOI： 10.1021/ja065325f
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419