Literature DB >> 17076475

La@C72 having a non-IPR carbon cage.

Takatsugu Wakahara1, Hidefumi Nikawa, Takashi Kikuchi, Tsukasa Nakahodo, G M Aminur Rahman, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Kenji Yoza, Ernst Horn, Kazunori Yamamoto, Naomi Mizorogi, Zdenek Slanina, Shigeru Nagase.   

Abstract

We show here that La@C72 has a non-IPR cage, unique electronic properties, and high reactivity by the spectroscopic and X-ray crystallographic analysis and the theoretical study. The isolation of La@C72 as a stable derivative might constitute an important stepping-stone on the way to isolation of these unknown metallofullerenes and open new material science of metallofullerenes.

Entities:  

Year:  2006        PMID: 17076475     DOI: 10.1021/ja064751y

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  5 in total

1.  Geometric and electronic structures of new endohedral fullerenes: Eu@C72.

Authors:  Mei Chi; Zhuxia Zhang; Peide Han; Xiaohong Fang; Wei Jia; Hongbiao Dong; Bingshe Xu
Journal:  J Mol Model       Date:  2008-04-15       Impact factor: 1.810

Review 2.  The stabilization of fused-pentagon fullerene molecules.

Authors:  Yuan-Zhi Tan; Su-Yuan Xie; Rong-Bin Huang; Lan-Sun Zheng
Journal:  Nat Chem       Date:  2009-08-24       Impact factor: 24.427

3.  Isolation and structure determination of missing fullerenes Gd@C74(CF3) n through in situ trifluoromethylation.

Authors:  Ayano Nakagawa; Shinobu Aoyagi; Haruka Omachi; Katsuma Ishino; Makiko Nishino; Jeremy Rio; Chris Ewels; Hisanori Shinohara
Journal:  R Soc Open Sci       Date:  2018-09-19       Impact factor: 2.963

4.  Eu@C72: Computed Comparable Populations of Two Non-IPR Isomers.

Authors:  Zdeněk Slanina; Filip Uhlík; Shigeru Nagase; Takeshi Akasaka; Ludwik Adamowicz; Xing Lu
Journal:  Molecules       Date:  2017-06-24       Impact factor: 4.411

5.  Stability computations for isomers of La@C(n) (n = 72, 74, 76).

Authors:  Zdeněk Slanina; Filip Uhlík; Shyi-Long Lee; Ludwik Adamowicz; Takeshi Akasaka; Shigeru Nagase
Journal:  Molecules       Date:  2012-11-05       Impact factor: 4.411

  5 in total

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