| Literature DB >> 17076470 |
José Martínez-Lillo1, Donatella Armentano, Giovanni De Munno, Wolfgang Wernsdorfer, Miguel Julve, Francesc Lloret, Juan Faus.
Abstract
The reaction of [ReIVCl4(ox)]2- and fully solvated Ni2+ ions in a MeCN/i-PrOH mixture affords the heterotetranuclear complex (NBu4)4[Ni{ReCl4(ox)}3] where the rhenium precursor acts as a bidentate ligand toward the nicke(II) ion through the oxalate group. The mixed 3d-5d species exhibits intramolecular ferromagnetic coupling and it behaves like a single-molecule magnet.Entities:
Year: 2006 PMID： 17076470 DOI： 10.1021/ja0643873
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419