Literature DB >> 17061866

Strong ferromagnetic exchange couplings in copper(II) and nickel(II) complexes with a paramagnetic tridentate chelate ligand, 2,2'-bipyridin-6-yl tert-butyl nitroxide.

Keita Osanai1, Atsushi Okazawa, Takashi Nogami, Takayuki Ishida.   

Abstract

A paramagnetic ligand 6bpyNO (2,2'-bipyridin-6-yl tert-butyl nitroxide) is a newcomer in the field of metal-radical hybrid magnetic materials. Complexes [CuII(6bpyNO)Cl2] and [NiII(6bpyNO)2](PF6)2 having highly planar chelate rings showed considerably strong ferromagnetic exchange couplings J/kB = 202 and 192 K, respectively, across the direct radical oxygen coordination bonds (the spin Hamiltonian is defined as -2JSi.Sj).

Entities:  

Year:  2006        PMID： 17061866     DOI： 10.1021/ja065623c

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  N-O chemistry for antibiotics: discovery of N-alkyl-N-(pyridin-2-yl)hydroxylamine scaffolds as selective antibacterial agents using nitroso Diels-Alder and ene chemistry.

Authors:  Timothy A Wencewicz; Baiyuan Yang; James R Rudloff; Allen G Oliver; Marvin J Miller
Journal:  J Med Chem       Date:  2011-09-15       Impact factor: 7.446

2.  A Hidden Coordination-Bond Torsional Deformation as a Sign of Possible Spin Transition in Nickel(II)-Bis(nitroxide) Compounds.

Authors:  Yukiya Kyoden; Takayuki Ishida
Journal:  Molecules       Date:  2020-08-20       Impact factor: 4.411

3.  An indication of spin-transition accompanied by an order-disorder structural transformation in [Ni(phpyNO)2(NCS)2] (phpyNO = tert-butyl 5-phenyl-2-pyridyl nitroxide).

Authors:  Yukiya Kyoden; Takayuki Ishida
Journal:  RSC Adv       Date:  2020-04-23       Impact factor: 3.361

4.  Radical enhancement of molecular thermoelectric efficiency.

Authors:  Sara Sangtarash; Hatef Sadeghi
Journal:  Nanoscale Adv       Date:  2020-01-26
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.