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Literature DB >> 17057853

Switching stereoselectivity in rhodium-catalysed 1,4-additions: The asymmetric synthesis of 2-substituted pyrrolizidinones.

Jonathan D Hargrave¹, Gerwyn Bish, Christopher G Frost.

Abstract

The appropriate choice of organometallic nucleophile enables the straightforward preparation of different stereoisomers of 2-substituted pyrrolizidinones utilising the rhodium-catalysed 1,4-addition reaction.

Entities: Chemical

Year: 2006 PMID： 17057853 DOI： 10.1039/b610128c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

3 in total

1. Rh-Catalyzed Conjugate Addition of Aryl and Alkenyl Boronic Acids to α-Methylene-β-lactones: Stereoselective Synthesis of trans-3,4-Disubstituted β-Lactones.

Authors: Christian A Malapit; Irungu K Luvaga; Donald R Caldwell; Nicholas K Schipper; Amy R Howell
Journal: Org Lett Date: 2017-08-15 Impact factor: 6.005

2. Trans-selective rhodium catalysed conjugate addition of organoboron reagents to dihydropyranones.

Authors: Hannah J Edwards; Sean Goggins; Christopher G Frost
Journal: Molecules Date: 2015-04-08 Impact factor: 4.411

3. Rh-Catalyzed Highly Enantioselective Synthesis of Aliphatic Sulfonyl Fluorides.

Authors: Balakrishna Moku; Wan-Yin Fang; Jing Leng; Linxian Li; Gao-Feng Zha; K P Rakesh; Hua-Li Qin
Journal: iScience Date: 2019-10-30

3 in total