Literature DB >> 17047844

A mechanistic rationalization of unusual kinetic behavior in proline-mediated C-O and C-N bond-forming reactions.

Suju P Mathew1, Martin Klussmann, Hiroshi Iwamura, David H Wells, Alan Armstrong, Donna G Blackmond.   

Abstract

Kinetic evidence supports the role of the reaction product in the catalytic cycle of proline-mediated alpha-aminoxylation and alpha-amination reactions, providing both design principles as well as a model for the evolution of efficiency in catalysis.

Entities:  

Year:  2006        PMID： 17047844     DOI： 10.1039/b609926b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

Review 1.  Quantum mechanical investigations of organocatalysis: mechanisms, reactivities, and selectivities.

Authors:  Paul Ha-Yeon Cheong; Claude Y Legault; Joann M Um; Nihan Çelebi-Ölçüm; K N Houk
Journal:  Chem Rev       Date:  2011-06-28       Impact factor: 60.622

Review 2.  Organocatalyzed asymmetric alpha-oxidation, alpha-aminoxylation and alpha-amination of carbonyl compounds.

Authors:  Tirayut Vilaivan; Worawan Bhanthumnavin
Journal:  Molecules       Date:  2010-02-11       Impact factor: 4.411

3.  Kinetics of cooperative CO2 adsorption in diamine-appended variants of the metal-organic framework Mg2(dobpdc).

Authors:  Jeffrey D Martell; Phillip J Milner; Rebecca L Siegelman; Jeffrey R Long
Journal:  Chem Sci       Date:  2020-03-31       Impact factor: 9.825

4.  A new charge-tagged proline-based organocatalyst for mechanistic studies using electrospray mass spectrometry.

Authors:  J Alexander Willms; Rita Beel; Martin L Schmidt; Christian Mundt; Marianne Engeser
Journal:  Beilstein J Org Chem       Date:  2014-08-28       Impact factor: 2.883
  4 in total

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