Literature DB >> 17047793

Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes.

Ryo Shintani1, Wei-Liang Duan, Soyoung Park, Tamio Hayashi.   

Abstract

A rhodium/binap complex has been found to effectively catalyze the isomerization of unactivated internal alkynes to the corresponding 1,3-dienes in the presence of an azomethine imine as the reaction promoter.

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Year:  2006        PMID： 17047793     DOI： 10.1039/b605368h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

Review 1.  Modern Synthetic Methods for the Stereoselective Construction of 1,3-Dienes.

Authors:  Raquel G Soengas; Humberto Rodríguez-Solla
Journal:  Molecules       Date:  2021-01-06       Impact factor: 4.411

2.  Phosphine-catalyzed divergent domino processes between γ-substituted allenoates and carbonyl-activated alkenes.

Authors:  Mingyue Wu; Zhaobin Han; Huanzhen Ni; Nengzhong Wang; Kuiling Ding; Yixin Lu
Journal:  Chem Sci       Date:  2022-02-11       Impact factor: 9.825

3.  Mechanistic Versatility at Ir(PSiP) Pincer Catalysts: Triflate Proton Shuttling from 2-Butyne to Diene and [3]Dendralene Motifs.

Authors:  José L Andrés; Elizabeth Suárez; Marta Martín; Eduardo Sola
Journal:  Organometallics       Date:  2022-09-13       Impact factor: 3.837

4.  Soft propargylic deprotonation: designed ligand enables Au-catalyzed isomerization of alkynes to 1,3-dienes.

Authors:  Zhixun Wang; Yanzhao Wang; Liming Zhang
Journal:  J Am Chem Soc       Date:  2014-06-17       Impact factor: 15.419

5.  Isomerization of Cyclooctadiene to Cyclooctyne with a Zinc/Zirconium Heterobimetallic Complex.

Authors:  Michael J Butler; Andrew J P White; Mark R Crimmin
Journal:  Angew Chem Int Ed Engl       Date:  2016-04-13       Impact factor: 15.336
  5 in total

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