| Literature DB >> 17036111 |
Jonathan D Hargrave1, Jennifer Herbert, Gerwyn Bish, Christopher G Frost.
Abstract
The cationic rhodium complex [Rh(cod)2][BF4] effectively catalyses the 1,4-addition of organotrialkoxysilanes to alpha-substituted acrylic esters. The reactions are promoted by heating in an oil-bath or more conveniently in a microwave reactor allowing rapid access to a useful range of functionalised products including 2-alkyl succinates and alpha-amino acid derivatives.Entities:
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Year: 2006 PMID： 17036111 DOI： 10.1039/b606977k
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876