Literature DB >> 17028760

Kinetic and thermodynamic parameters for the equilibrium reactions of phenols with the dpph. radical.

Mario C Foti1, Carmelo Daquino.   

Abstract

The kinetics and energetics of the reversible reaction of phenols with the dpph. radical have been studied; steric shielding of the divalent N by the o-NO2 in dpph. seems to be the main cause of the entropic barriers of this reaction.

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Year:  2006        PMID: 17028760     DOI: 10.1039/b606322e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  5 in total

Review 1.  Thermochemistry of proton-coupled electron transfer reagents and its implications.

Authors:  Jeffrey J Warren; Tristan A Tronic; James M Mayer
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2.  A Kinetic Approach in the Evaluation of Radical-Scavenging Efficiency of Sinapic Acid and Its Derivatives.

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Journal:  Molecules       Date:  2017-02-28       Impact factor: 4.411

Review 3.  The Chemistry of DPPH· Free Radical and Congeners.

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Journal:  Int J Mol Sci       Date:  2021-02-03       Impact factor: 5.923

4.  Concentration-dependent HAT/ET mechanism of the reaction of phenols with 2,2-diphenyl-1-picrylhydrazyl (dpph˙) in methanol.

Authors:  Paweł Przybylski; Adrian Konopko; Piotr Łętowski; Katarzyna Jodko-Piórecka; Grzegorz Litwinienko
Journal:  RSC Adv       Date:  2022-03-15       Impact factor: 3.361

5.  Unexpected Role of pH and Microenvironment on the Antioxidant and Synergistic Activity of Resveratrol in Model Micellar and Liposomal Systems.

Authors:  Adrian Konopko; Grzegorz Litwinienko
Journal:  J Org Chem       Date:  2021-11-29       Impact factor: 4.354

  5 in total

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