Literature DB >> 17028753

An outstanding catalyst for asymmetric transfer hydrogenation in aqueous solution and formic acid/triethylamine.

Daljit S Matharu1, David J Morris, Guy J Clarkson, Martin Wills.   

Abstract

A Rh/tetramethylcyclopentadienyl complex containing a tethered functionality has been demonstrated to give excellent results in the asymmetric transfer hydrogenation of ketones in both aqueous and formic acid/triethylamine media.

Entities:  

Year:  2006        PMID： 17028753     DOI： 10.1039/b606288a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Kinetic resolution of secondary alcohols using amidine-based catalysts.

Authors:  Ximin Li; Hui Jiang; Eric W Uffman; Lei Guo; Yuhua Zhang; Xing Yang; Vladimir B Birman
Journal:  J Org Chem       Date:  2012-02-09       Impact factor: 4.354

2.  Enantioselective, ketoreductase-based entry into pharmaceutical building blocks: ethanol as tunable nicotinamide reductant.

Authors:  Sylvain Broussy; Ross W Cheloha; David B Berkowitz
Journal:  Org Lett       Date:  2009-01-15       Impact factor: 6.005

3.  Dehydrogenation, disproportionation and transfer hydrogenation reactions of formic acid catalyzed by molybdenum hydride compounds.

Authors:  Michelle C Neary; Gerard Parkin
Journal:  Chem Sci       Date:  2015-01-14       Impact factor: 9.825
  3 in total

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