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Literature DB >> 17025327

Molecular iodine-catalyzed facile procedure for N-Boc protection of amines.

Ravi Varala¹, Sreelatha Nuvula, Srinivas R Adapa.

Abstract

An efficient and practical protocol for the protection of various structurally and electronically divergent aryl and aliphatic amines using (Boc)2O in the presence of a catalytic amount of molecular iodine (10 mol %) under solvent-free conditions at ambient temperature is presented.

Entities: Chemical Gene

Year: 2006 PMID： 17025327 DOI： 10.1021/jo0612473

Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354

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Cited

6 in total

1. Antimicrobial screening to molecular docking of newly synthesized ferrocenyl-substituted pyrazole.

Authors: Shashi Sharma; Hardeep Singh Tuli; Mehmet Varol; Pallvi Agarwal; Anita Rani; Zahoor Abbas; Manoj Kumar
Journal: Int J Health Sci (Qassim) Date: 2022 Jul-Aug

2. Enzymatic kinetic resolution of tert-butyl 2-(1-hydroxyethyl)phenylcarbamate, a key intermediate to chiral organoselenanes and organotelluranes.

Authors: Leandro Piovan; Monica D Pasquini; Leandro H Andrade
Journal: Molecules Date: 2011-09-20 Impact factor: 4.411

6. Magnetically Recoverable Silica-Decorated Ferromagnetic-Nanoceria Nanocatalysts and Their Use with O- and N-Butyloxycarbonylation Reaction via Solvent-Free Condition.

Authors: Shripad M Patil; Runjhun Tandon; Nitin Tandon
Journal: ACS Omega Date: 2022-07-07

6 in total

Molecular iodine-catalyzed facile procedure for N-Boc protection of amines.

1. Antimicrobial screening to molecular docking of newly synthesized ferrocenyl-substituted pyrazole.

2. Enzymatic kinetic resolution of tert-butyl 2-(1-hydroxyethyl)phenylcarbamate, a key intermediate to chiral organoselenanes and organotelluranes.

3. Mild deprotection of the N-tert-butyloxycarbonyl (N-Boc) group using oxalyl chloride.

4. Me₃SI-promoted chemoselective deacetylation: a general and mild protocol.

5. Iodine-catalyzed efficient synthesis of xanthene/thioxanthene-indole derivatives under mild conditions.

6. Magnetically Recoverable Silica-Decorated Ferromagnetic-Nanoceria Nanocatalysts and Their Use with O- and N-Butyloxycarbonylation Reaction via Solvent-Free Condition.

Molecular iodine-catalyzed facile procedure for N-Boc protection of amines.

1. Antimicrobial screening to molecular docking of newly synthesized ferrocenyl-substituted pyrazole.

2. Enzymatic kinetic resolution of tert-butyl 2-(1-hydroxyethyl)phenylcarbamate, a key intermediate to chiral organoselenanes and organotelluranes.

3. Mild deprotection of the N-tert-butyloxycarbonyl (N-Boc) group using oxalyl chloride.

4. Me3SI-promoted chemoselective deacetylation: a general and mild protocol.

5. Iodine-catalyzed efficient synthesis of xanthene/thioxanthene-indole derivatives under mild conditions.

6. Magnetically Recoverable Silica-Decorated Ferromagnetic-Nanoceria Nanocatalysts and Their Use with O- and N-Butyloxycarbonylation Reaction via Solvent-Free Condition.

4. Me₃SI-promoted chemoselective deacetylation: a general and mild protocol.