Literature DB >> 17003884

NiII(TPA) as an efficient catalyst for alkane hydroxylation with m-CPBA.

Takayuki Nagataki1, Yoshimitsu Tachi, Shinobu Itoh.   

Abstract

A simple Ni(II)(TPA) complex [TPA = tris(2-pyridylmethyl)amine] has been demonstrated to act as an efficient turnover catalyst for alkane hydroxylation with m-CPBA (m-chloroperbenzoic acid), in which contribution of a NiO(+) (nickel-oxo) type active oxygen species is suggested.

Entities:  

Year:  2006        PMID: 17003884     DOI: 10.1039/b608311k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  8 in total

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2.  Characterization and reactivity of a terminal nickel(III)-oxygen adduct.

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Journal:  Chemistry       Date:  2015-01-22       Impact factor: 5.236

3.  Spectroscopic capture and reactivity of a low-spin cobalt(IV)-oxo complex stabilized by binding redox-inactive metal ions.

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4.  Evaluating Metal-Ligand Interactions of Metal-Binding Isosteres Using Model Complexes.

Authors:  Hyeonglim Seo; Kathleen E Prosser; Mark Kalaj; Johannes Karges; Benjamin L Dick; Seth M Cohen
Journal:  Inorg Chem       Date:  2021-10-26       Impact factor: 5.165

5.  Bis(thio-cyanato-κN)[tris-(2-pyridylmeth-yl)amine-κN,N',N'',N''']nickel(II) methanol hemisolvate.

Authors:  Sajini R Randeniya; Richard E Norman
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6.  Cobalt(II) Complexes with N,N,N-Scorpionates and Bidentate Ligands: Comparison of Hydrotris(3,5-dimethylpyrazol-1-yl)borate Tp* vs. Phenyltris(4,4-dimethyloxazolin-2-yl)borate ToM to Control the Structural Properties and Reactivities of Cobalt Centers.

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Journal:  Molecules       Date:  2018-06-16       Impact factor: 4.411

7.  Catalytic Hydroxylation of Polyethylenes.

Authors:  Ala Bunescu; Sunwoo Lee; Qian Li; John F Hartwig
Journal:  ACS Cent Sci       Date:  2017-08-09       Impact factor: 14.553

8.  Electronic structure and reactivity of nickel(i) pincer complexes: their aerobic transformation to peroxo species and site selective C-H oxygenation.

Authors:  Christoph A Rettenmeier; Hubert Wadepohl; Lutz H Gade
Journal:  Chem Sci       Date:  2016-02-11       Impact factor: 9.825

  8 in total

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