| Literature DB >> 17002345 |
Jonathan L Sessler1, Dong-Gyu Cho, Marcin Stepień, Vincent Lynch, Jacek Waluk, Zin Seok Yoon, Dongho Kim.
Abstract
The synthesis of an inverted, methoxylated sapphyrin derivative is described. This system, wherein inversion of pyrrolic nitrogen atoms is configurationally enforced via the use of a 3,3'-bipyrrolic precursor, displays what is best described as "weak aromaticity" as judged from its spectroscopic features and supporting theoretical calculations.Entities:
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Year: 2006 PMID: 17002345 PMCID: PMC2526041 DOI: 10.1021/ja064675z
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419