Literature DB >> 16986938

Heliespirones B and C: two new plant heliespiranes with a novel spiro heterocyclic sesquiterpene skeleton.

Francisco A Macías1, José L G Galindo, Rosa M Varela, Ascensión Torres, José M G Molinillo, Frank R Fronczek.   

Abstract

From the medium, polar bioactive fractions of leaf aqueous extract of Helianthus annuus L., heliespirones B (2) and C (3) have been isolated. The structural elucidation was based on extensive spectral studies. A probable biogenesis of heliespirone skeleton is proposed and discussed. The structure of heliespirone B has been confirmed by X-ray diffraction analysis.

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Year:  2006        PMID: 16986938     DOI: 10.1021/ol061673a

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  4 in total

1.  Allelopathy: The Chemical Language of Plants.

Authors:  Francisco A Macías; Alexandra G Durán; José M G Molinillo
Journal:  Prog Chem Org Nat Prod       Date:  2020

2.  New strategies for natural products containing chroman spiroketals.

Authors:  Jason C Green; G Leslie Burnett; Thomas R R Pettus
Journal:  Pure Appl Chem       Date:  2012       Impact factor: 2.453

3.  Elucidation of the regio- and chemoselectivity of enzymatic allylic oxidations with Pleurotus sapidus - conversion of selected spirocyclic terpenoids and computational analysis.

Authors:  Verena Weidmann; Mathias Schaffrath; Holger Zorn; Julia Rehbein; Wolfgang Maison
Journal:  Beilstein J Org Chem       Date:  2013-10-29       Impact factor: 2.883

Review 4.  Spirocyclic Motifs in Natural Products.

Authors:  Evgeny Chupakhin; Olga Babich; Alexander Prosekov; Lyudmila Asyakina; Mikhail Krasavin
Journal:  Molecules       Date:  2019-11-17       Impact factor: 4.411

  4 in total

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