| Literature DB >> 16986931 |
Birgit Gockel1, Norbert Krause.
Abstract
The gold(I)-catalyzed 6-endo cycloisomerization of beta-hydroxyallenes provides a mild and efficient access to chiral functionalized dihydropyrans which were obtained at room temperature in good chemical yields with axis-to-center chirality transfer. The method was extended to the beta-aminoallene 12, which afforded tetrahydropyridine 13 in good yield as well.Entities:
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Year: 2006 PMID： 16986931 DOI： 10.1021/ol061669z
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005