| Literature DB >> 16967937 |
Melanie C Denney1, Vincent Pons, Travis J Hebden, D Michael Heinekey, Karen I Goldberg.
Abstract
In the presence of an iridium pincer complex, dehydrogenation of ammonia borane (H3NBH3) occurs rapidly at room temperature in tetrahydrofuran to generate 1.0 equivalent of H2 and [NH2BH2]5. A metal borohydride complex has been isolated as a dormant form of the catalyst which can be reactivated by reaction with H2.Entities:
Year: 2006 PMID： 16967937 DOI： 10.1021/ja062419g
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419