Literature DB >> 16953614

Highly efficient Rh(I)-catalyzed asymmetric hydrogenation of enamines using monodente spiro phosphonite ligands.

Guo-Hua Hou1, Jian-Hua Xie, Li-Xin Wang, Qi-Lin Zhou.   

Abstract

A highly enantioselective hydrogenation of nonfunctionalized enamines has been developed by using rhodium complexes of chiral spiro phosphonite ligands, providing chiral tertiary amines in excellent enantioselectivities.

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Year:  2006        PMID: 16953614     DOI: 10.1021/ja0644778

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  1 in total

1.  Hydrogenation of unactivated enamines to tertiary amines: rhodium complexes of fluorinated phosphines give marked improvements in catalytic activity.

Authors:  Sergey Tin; Tamara Fanjul; Matthew L Clarke
Journal:  Beilstein J Org Chem       Date:  2015-05-05       Impact factor: 2.883

  1 in total

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