Literature DB >> 16933896

Heterotopic helicand for designing heterometallic helicates.

Paula Cucos1, Mirela Pascu, Roberta Sessoli, Narcis Avarvari, Fabrice Pointillart, Marius Andruh.   

Abstract

A new diazine tetratopic helicand, H4L, is obtained from 3-formylsalicylic acid and hydrazine. The reaction between H4L and cobalt(II) perchlorate, iron(III) perchlorate, and sodium carbonate leads to triple-stranded tetranuclear anionic helicates, [L3Co(II)2Fe(III)2]2-, which are connected through Na ions, resulting in chiral coordination polymers, [L3Na2Fe2Co2(H2O)4(EtOH)2].3H2O.

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Year:  2006        PMID: 16933896     DOI: 10.1021/ic060533u

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  1 in total

1.  2,2'-Dihydroxy-3,3'-[(1E,1'E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate.

Authors:  Sheng-Sen Zhang; Geng-Jin-Sheng Cheng; Yu Lei; Yin-Bao Li
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-12-24
  1 in total

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